ADSORPTION OF MERCURY (II) FROM AQUEOUS SOLUTION BY CRUMB RUBBER SLUDGE: ISOTHERM AND KINETIC STUDIES
DOI:
https://doi.org/10.70248/jdaics.v2i1.1785Keywords:
Adsorption, Crumb rubber sludge, Isotherm, Kinetic, MercuryAbstract
The use of two different crumb rubber adsorbent (CRS), pure crumb rubber sludge (pCRS) and modified crumb rubber sludge (mPCRS) with HNO3 activator was investigated for the removal of Hg(II) from aqueous solution. Batch experiment was conducted to analyze the effect of adsorbent dosage and contact time on the adsorption capacities of pCRS and mCRS. Adsorption isotherm and adsorption kinetics was also analyzed to get description of the adsorption mechanism and the adsorbent properties. The Langmuir isotherm provided the best correlation with the maximum adsorption capacity was 16.00 mg/g an, 17.513 mg/g for respected to pCRS and mCRS. The kinetics studies showed that the Hg(II) for both adsorbents adsorbed rapidly which can be adjusted to the pseudo second order model. Our current study confirmed that CRS was effective adsorbent for the removal of Hg(II) from aqueous solution which followed monolayer and multilayer chemisorption
References
S. Sy, Harmiwati, D. Kurniawati, H. Aziz, Z. Chaidir, and R. Zein, “Removal of Zinc onto Several adsorbents derived from waste activated sludge of crumb rubber industry (CRI-WAS),” Int. J. Adv. Sci. Eng. Inf. Technol., vol. 8, no. 1, pp. 157–164, 2018.
S. Sy, D. Kurniawati, I. Lestari, H. Harmiwati, and M. Kasman, “Pengaruh pH dan dosis adsorben dari limbah lumpur aktif industri crumb rubber terhadap kapasitas penyerapan ion Cd(II) dan Zn(II),” J. Litbang Ind., vol. 8, no. 2, p. 95, 2018.
C. Yang, J. Wang, M. Lei, G. Xie, G. Zeng, and S. Luo, “Biosorption of zinc(II) from aqueous solution by dried activated sludge,” J. Environ. Sci., vol. 22, no. 5, pp. 675–680, 2010.
H. Benaïssa and M. A. Elouchdi, “Biosorption of copper (II) ions from synthetic aqueous solutions by drying bed activated sludge,” J. Hazard. Mater., vol. 194, pp. 69–78, 2011.
M. Hunsom and C. Autthanit, “Adsorptive purification of crude glycerol by sewage sludge-derived activated carbon prepared by chemical activation with H3PO4, K2CO3 and KOH,” Chem. Eng. J., vol. 229, pp. 334–343, 2013.
V. M. Monsalvo, A. F. Mohedano, and J. J. Rodriguez, “Activated carbons from sewage sludge. Application to aqueous-phase adsorption of 4-chlorophenol,” Desalination, vol. 277, no. 1–3, pp. 377–382, 2011.
M. A. A. Zaini, M. Zakaria, S. H. Mohd.-Setapar, and M. A. Che-Yunus, “Sludge-adsorbents from palm oil mill effluent for methylene blue removal,” J. Environ. Chem. Eng., vol. 1, no. 4, pp. 1091–1098, 2013.
S. Zhu et al., “Valorization of manganese-containing groundwater treatment sludge by preparing magnetic adsorbent for Cu(II) adsorption,” J. Environ. Manage., vol. 236, no. August 2018, pp. 446–454, 2019.
C. Zhao et al., A novel activated sludge-graphene oxide composites for the removal of uranium(VI) from aqueous solutions, vol. 271, no. Vi. Elsevier B.V, 2018.
R. Kumar et al., “Waste sludge derived adsorbents for arsenate removal from water,” Chemosphere, vol. 239, p. 124832, 2020.
J. Liu, Z. Huang, Z. Chen, J. Sun, Y. Gao, and E. Wu, “Resource utilization of swine sludge to prepare modified biochar adsorbent for the efficient removal of Pb(II) from water,” J. Clean. Prod., vol. 257, p. 120322, 2020.
J. Ifthikar et al., “Highly Efficient Lead Distribution by Magnetic Sewage Sludge Biochar: Sorption Mechanisms and Bench Applications,” Bioresour. Technol., vol. 238, pp. 399–406, 2017.
H. Zare, H. Heydarzade, M. Rahimnejad, A. Tardast, M. Seyfi, and S. M. Peyghambarzadeh, “Dried activated sludge as an appropriate biosorbent for removal of copper (II) ions,” Arab. J. Chem., vol. 8, no. 6, pp. 858–864, 2015.
S. Sy, Sofyan, Ardinal, Harmiwati, M. Kasman, and R. Zein, “The ability of three types of adsorbents prepared from waste activated sludge of crumb rubber industry (CRI-WAS) for Cd(II) ion removal,” AIP Conf. Proc., vol. 2049, no. Ii, 2018.
D. Patiño-Ruiz, H. Bonfante, G. De Ávila, and A. Herrera, “Adsorption kinetics, isotherms and desorption studies of mercury from aqueous solution at different temperatures on magnetic sodium alginate-thiourea microbeads,” Environ. Nanotechnology, Monit. Manag., vol. 12, no. July, p. 100243, 2019.
N. M. Mora Alvarez, J. M. Pastrana, Y. Lagos, and J. J. Lozada, “Evaluation of mercury (Hg2+) adsorption capacity using exhausted coffee waste,” Sustain. Chem. Pharm., vol. 10, no. September, pp. 60–70, 2018.
M. Arshadi, “Manganese chloride nanoparticles: A practical adsorbent for the sequestration of Hg(II) ions from aqueous solution,” Chem. Eng. J., vol. 259, pp. 170–182, 2015.
Y. Guo, J. Deng, J. Zhu, X. Zhou, and R. Bai, “Removal of mercury(II) and methylene blue from a wastewater environment with magnetic graphene oxide: Adsorption kinetics, isotherms and mechanism,” RSC Adv., vol. 6, no. 86, pp. 82523–82536, 2016.
G. Tan, W. Sun, Y. Xu, H. Wang, and N. Xu, “Sorption of mercury (II) and atrazine by biochar, modified biochars and biochar based activated carbon in aqueous solution,” Bioresour. Technol., vol. 211, no. Ii, pp. 727–735, 2016.
T. Aprianti, B. D. Afrah, and T. E. Agustina, “Acid mine drainage treatment using activated carbon ceramic adsorbent in adsorption column,” Int. J. Adv. Sci. Eng. Inf. Technol., vol. 7, no. 4, pp. 1241–1247, 2017.
Y. Sun et al., “Adsorption of mercury (II) from aqueous solutions using FeS and pyrite: A comparative study,” Chemosphere, vol. 185, no. Ii, pp. 452–461, 2017.
T. Sheela, Y. A. Nayaka, R. Viswanatha, S. Basavanna, and T. G. Venkatesha, “Kinetics and thermodynamics studies on the adsorption of Zn(II), Cd(II) and Hg(II) from aqueous solution using zinc oxide nanoparticles,” Powder Technol., vol. 217, pp. 163–170, 2012.
Y. Fransiscus, R. K. Widi, G. O. Aprilasti, and M. D. Yuharma, “Adsorption of phosphate in aqueous solutions using manganese dioxide,” Int. J. Adv. Sci. Eng. Inf. Technol., vol. 8, no. 3, pp. 818–824, 2018.
S. Pan, H. Shen, Q. Xu, J. Luo, and M. Hu, “Surface mercapto engineered magnetic Fe3O4 nanoadsorbent for the removal of mercury from aqueous solutions,” J. Colloid Interface Sci., vol. 365, no. 1, pp. 204–212, 2012.
M. Zabihi, A. Haghighi Asl, and A. Ahmadpour, “Studies on adsorption of mercury from aqueous solution on activated carbons prepared from walnut shell,” J. Hazard. Mater., vol. 174, no. 1–3, pp. 251–256, 2010.
K. K. Wong, C. K. Lee, K. S. Low, and M. J. Haron, “Removal of Cu and Pb by tartaric acid modified rice husk from aqueous solutions,” Chemosphere, vol. 50, no. 1, pp. 23–28, 2003.
E. K. Faulconer, N. V. H. von Reitzenstein, and D. W. Mazyck, “Optimization of magnetic powdered activated carbon for aqueous Hg(II) removal and magnetic recovery,” J. Hazard. Mater., vol. 199–200, pp. 9–14, 2012.
D. K. Mondal, B. K. Nandi, and M. K. Purkait, “Removal of mercury (II) from aqueous solution using bamboo leaf powder: Equilibrium, thermodynamic and kinetic studies,” J. Environ. Chem. Eng., vol. 1, no. 4, pp. 891–898, 2013.
